Preheat oven to 350 degrees Line two rimmed cookie sheets with foil. Grease foil and set aside.
In a medium saucepan, combine sugar, butter, coconut milk and maple syrup. Cook over low heat for about 5 minutes or until sugar is dissolved, stirring near constantly.
Bring to a boil. To prevent sugar from crystallizing, brush down sides of saucepan with a wet pastry brush. Cook until thermometer registers 238 degrees. Remove from heat and immediately stir in quinoa flakes, quinoa, almonds, coconut, flour, lemon peel and vanilla extract.
Drop by the tablespoon on prepared pans. (Keep about 3 inches apart) With a fork dipped in cold water, flatten the cookies. Bake for 5 minutes. Switch racks and bake for 3 to 5 minutes longer.
Cool on baking sheets and then lift from foil. Place on a large sheet of parchment paper.
Place chocolate in the top of a double boiler and melt over simmering water. Stir in cayenne pepper. Drizzle cookies with chocolate and let sit until chocolate has set.